Issue 12, 2015

Organopolymerization of naturally occurring Tulipalin B: a hydroxyl-functionalized methylene butyrolactone

Abstract

The first successful polymerization of the naturally occurring, OH-containing, tri-functional monomer Tulipalin B (βHMBL) is established. N-Heterocyclic carbene and phosphazene superbase catalysts effectively polymerize βHMBL into polymers with Mn up to 13.2 kg mol−1. The possible polymer structure is thought to be a branched copolymer of poly(vinyl-ether lactone)s, derived from proposed crossovers between conjugate Michael and oxa-Michael additions, enabled by proton transfer.

Graphical abstract: Organopolymerization of naturally occurring Tulipalin B: a hydroxyl-functionalized methylene butyrolactone

Supplementary files

Article information

Article type
Research Article
Submitted
23 ⵖⵓⵛ 2015
Accepted
02 ⵏⵓⵡ 2015
First published
06 ⵏⵓⵡ 2015

Org. Chem. Front., 2015,2, 1625-1631

Organopolymerization of naturally occurring Tulipalin B: a hydroxyl-functionalized methylene butyrolactone

J. Tang and E. Y.-X. Chen, Org. Chem. Front., 2015, 2, 1625 DOI: 10.1039/C5QO00262A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements