Issue 7, 2014

Radical vinylation of dioxolanes and N-acylpyrrolidines using vinyl bromides

Abstract

Radical vinylation was investigated using vinyl bromides with an electron-withdrawing substituent at the β-position. The vinylation of 1,3-dioxolanes proceeded well to give 2-vinyl-1,3-dioxolanes in good yields. The α-vinylation of N-acylpyrrolidines also proceeded well to give 2-vinyl-N-acylpyrrolidines.

Graphical abstract: Radical vinylation of dioxolanes and N-acylpyrrolidines using vinyl bromides

Supplementary files

Article information

Article type
Research Article
Submitted
13 ⵎⴰⵢ 2014
Accepted
18 ⵢⵓⵏ 2014
First published
19 ⵢⵓⵏ 2014

Org. Chem. Front., 2014,1, 755-758

Author version available

Radical vinylation of dioxolanes and N-acylpyrrolidines using vinyl bromides

T. Kippo, Y. Kimura, A. Maeda, H. Matsubara, T. Fukuyama and I. Ryu, Org. Chem. Front., 2014, 1, 755 DOI: 10.1039/C4QO00138A

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