Issue 18, 2018

Photoinduced fragmentation-rearrangement sequence of cycloketoxime esters

Abstract

A novel rearrangement of cycloketoxime esters to cyano-containing benzoates beyond the traditional Beckmann and Neber rearrangement process has been established in the presence of photocatalysis catalysis. This SET-induced structural reorganization of cycloketoxime esters is perfectly an atom economic process and distinguished by mild and safe reaction conditions that avoid acid, base and toxic cyanide salts.

Graphical abstract: Photoinduced fragmentation-rearrangement sequence of cycloketoxime esters

Supplementary files

Article information

Article type
Research Article
Submitted
21 ⵢⵓⵍ 2018
Accepted
16 ⵖⵓⵛ 2018
First published
16 ⵖⵓⵛ 2018

Org. Chem. Front., 2018,5, 2719-2722

Photoinduced fragmentation-rearrangement sequence of cycloketoxime esters

B. Zhao, C. Chen, J. Lv, Z. Li, Y. Yuan and Z. Shi, Org. Chem. Front., 2018, 5, 2719 DOI: 10.1039/C8QO00747K

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