Issue 10, 2015

‘All three-in-one’: ferromagnetic interactions, single-molecule magnetism and magnetocaloric properties in a new family of [Cu4Ln] (LnIII = Gd, Tb, Dy) clusters

Abstract

A new family of isomorphous [Cu4Ln] clusters (LnIII = Gd, Tb, Dy) with a ‘propeller’-like topology was obtained from the use of naphthalene-2,3-diol in CuII/LnIII chemistry; all complexes are ferromagnetically-coupled and display either magnetocaloric properties or SMM behavior depending on the central Ln ion.

Graphical abstract: ‘All three-in-one’: ferromagnetic interactions, single-molecule magnetism and magnetocaloric properties in a new family of [Cu4Ln] (LnIII = Gd, Tb, Dy) clusters

Supplementary files

Article information

Article type
Research Article
Submitted
12 ⵖⵓⵛ 2015
Accepted
08 ⵛⵓⵜ 2015
First published
09 ⵛⵓⵜ 2015

Inorg. Chem. Front., 2015,2, 945-948

Author version available

‘All three-in-one’: ferromagnetic interactions, single-molecule magnetism and magnetocaloric properties in a new family of [Cu4Ln] (LnIII = Gd, Tb, Dy) clusters

P. Richardson, D. I. Alexandropoulos, L. Cunha-Silva, G. Lorusso, M. Evangelisti, J. Tang and T. C. Stamatatos, Inorg. Chem. Front., 2015, 2, 945 DOI: 10.1039/C5QI00146C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements