Issue 41, 2018

A series of dithiocarbamates for americium, curium, and californium

Abstract

Characterizing how actinide properties change across the f-element series is critical for improving predictive capabilities and solving many nuclear problems facing our society. Unfortunately, it is difficult to make direct comparisons across the 5f-element series because so little is known about trans-plutonium elements. Results described herein help to address this issue through isolation of An(S2CNEt2)3(N2C12H8) (Am, Cm, and Cf). These findings included the first single crystal X-ray diffraction measurements of Cm–S (mean of 2.86 ± 0.04 Å) and Cf–S (mean of 2.84 ± 0.04 Å) bond distances. Furthermore, they highlight the potential of An(S2CNEt2)3(N2C12H8) for providing a test bed for comparative analyses of actinide versus lanthanide bonding interactions.

Graphical abstract: A series of dithiocarbamates for americium, curium, and californium

Supplementary files

Article information

Article type
Paper
Submitted
29 Чер 2018
Accepted
20 Сер 2018
First published
31 Сер 2018

Dalton Trans., 2018,47, 14452-14461

Author version available

A series of dithiocarbamates for americium, curium, and californium

S. K. Cary, J. Su, S. S. Galley, T. E. Albrecht-Schmitt, E. R. Batista, M. G. Ferrier, S. A. Kozimor, V. Mocko, B. L. Scott, C. E. Van Alstine, F. D. White and P. Yang, Dalton Trans., 2018, 47, 14452 DOI: 10.1039/C8DT02658K

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