Issue 66, 2024

Combining Ti4(embonate)6 anionic cages and π-conjugated coordination cations for highly effective optical limiting

Abstract

The integration of anionic Ti4L6 (L = embonate) cages and π-conjugated coordination cations into ordered structures can produce high-performance nonlinear optical (NLO) materials. More specifically, by employing Ti4L6 cages for assembly with mixed N,N-chelated and P,P-chelated type conjugated organic ligands and Ag+ ions, three cage-based structures have been synthesized and structurally characterized. Among them, an ion pair structure with strong π–π accumulation exhibits a significant third-order NLO response, and an excellent optical limiting effect has been experimentally verified. This work provides a promising material for NLO applications.

Graphical abstract: Combining Ti4(embonate)6 anionic cages and π-conjugated coordination cations for highly effective optical limiting

Supplementary files

Article information

Article type
Communication
Submitted
18 Kho 2024
Accepted
17 Maw 2024
First published
24 Maw 2024

Chem. Commun., 2024,60, 8748-8751

Combining Ti4(embonate)6 anionic cages and π-conjugated coordination cations for highly effective optical limiting

Y. Yuan, D. Zhang, Q. Li, S. Chen, Y. He and J. Zhang, Chem. Commun., 2024, 60, 8748 DOI: 10.1039/D4CC02938K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements