Issue 25, 2015

Application of a nucleophilic boryl complex in the frustrated Lewis pair: activation of H–H, B–H and C[double bond, length as m-dash]C bonds with B(C6F5)3 and boryl–borate lithium

Abstract

The frustrated Lewis pair comprised of B(C6F5)3 and a boryl–borate lithium salt Li[pinBB(Ph)pin] can efficiently activate dihydrogen, pinacolborane and ethylene at ambient temperature. Theoretical studies suggest that the nucleophilic sp2 boryl moiety of Li[pinBB(Ph)pin] plays different roles in these reactions.

Graphical abstract: Application of a nucleophilic boryl complex in the frustrated Lewis pair: activation of H–H, B–H and C [[double bond, length as m-dash]] C bonds with B(C6F5)3 and boryl–borate lithium

Supplementary files

Article information

Article type
Communication
Submitted
28 Ndz 2014
Accepted
17 Huk 2014
First published
18 Huk 2014

Chem. Commun., 2015,51, 5505-5508

Author version available

Application of a nucleophilic boryl complex in the frustrated Lewis pair: activation of H–H, B–H and C[double bond, length as m-dash]C bonds with B(C6F5)3 and boryl–borate lithium

J. Zheng, Y. Wang, Z. H. Li and H. Wang, Chem. Commun., 2015, 51, 5505 DOI: 10.1039/C4CC07658C

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