Issue 9, 2018

Asymmetric total syntheses of callistrilones B, G and J

Abstract

A very concise approach for the first asymmetric and scalable total syntheses of callistrilones B, G and J has been developed. These syntheses proceeded in only 3–4 steps from the commercially available (−)-α-phellandrene (8), without the need for protecting groups. The key feature of the syntheses was a biomimetic, diastereo- and regioselective oxidative [3 + 2] cycloaddition.

Graphical abstract: Asymmetric total syntheses of callistrilones B, G and J

Supplementary files

Article information

Article type
Research Article
Submitted
04 Şub 2018
Accepted
14 Mar 2018
First published
15 Mar 2018

Org. Chem. Front., 2018,5, 1506-1510

Asymmetric total syntheses of callistrilones B, G and J

L. Hu, M. Cheng, J. Cao, L. Zhong, Y. Hu, Y. Wang, L. Wang, W. Ye and C. Li, Org. Chem. Front., 2018, 5, 1506 DOI: 10.1039/C8QO00130H

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