Issue 57, 2024

Catalytic effect of microflow space for supramolecular block co-polymerization of water-soluble porphyrins

Abstract

Using microflow space, a catalytic effect was achieved for supramolecular polymerization. With increasing reactivity at the polymer end, the selective connection of active monomers formed new block domains, avoiding fast homo-assembly. Binding of less-reactive monomers at the polymer end overcame steric bulkiness, affording a stable supramolecular diblock copolymer (SdiBCP).

Graphical abstract: Catalytic effect of microflow space for supramolecular block co-polymerization of water-soluble porphyrins

Supplementary files

Article information

Article type
Communication
Submitted
26 เม.ย. 2567
Accepted
27 พ.ค. 2567
First published
29 พ.ค. 2567

Chem. Commun., 2024,60, 7303-7306

Catalytic effect of microflow space for supramolecular block co-polymerization of water-soluble porphyrins

H. Takemori, C. Kanzaki, S. Nomura, T. Maeda and M. Numata, Chem. Commun., 2024, 60, 7303 DOI: 10.1039/D4CC02003K

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