Issue 57, 2024
From the journal:

Chemical Communications

A bridging bis-phosphanido-phosphinidene complex of lanthanum supported by a sterically encumbering PN ligand†

B. Wittwer,a   F. Heim,a   K. Wursta  and  S. Hohloch ORCID logo *a  

* Corresponding authors

a University of Innsbruck, Center for Chemistry and Biomedicine, Department of General, Inorganic and Theoretical Chemistry, Innrain 80–82, 6020 Innsbruck, Austria
E-mail: Stephan.Hohloch@uibk.ac.at

Abstract

Synthesis of a bulky anilidophosphine ligand (short PNTerph) and its lanthanum complexes 1 and 3 is reported. When exposed to KPHMes, both complexes form the first example of a bis-phosphanido-phosphinidene complex 2. This complex undergoes Phospha-Wittig type reactions and its reactivity towards strong bases is further investigated.

Graphical abstract: A bridging bis-phosphanido-phosphinidene complex of lanthanum supported by a sterically encumbering PN ligand

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Article information

DOI
https://doi.org/10.1039/D4CC02244K
Article type
Communication
Submitted
08 May 2024
Accepted
29 May 2024
First published
30 May 2024
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2024,60, 7299-7302

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A bridging bis-phosphanido-phosphinidene complex of lanthanum supported by a sterically encumbering PN ligand

B. Wittwer, F. Heim, K. Wurst and S. Hohloch, Chem. Commun., 2024, 60, 7299 DOI: 10.1039/D4CC02244K

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