Themed collection Journal of Materials Chemistry A Recent Review Articles

Topological quantum materials in catalysis
Let's quantum: topological quantum materials offer high electron mobility, stable surface states, and resistance to contamination, making them ideal candidates for next-generation heterogeneous catalysts.
J. Mater. Chem. A, 2025,13, 6325-6341
https://doi.org/10.1039/D4TA08325C
Precise Design of MOF-Derived Single Atom Catalysts with Symmetric and Asymmetric Coordination for Advanced Lithium-Sulfur Batteries
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA05134G

Decoding pH-dependent electrocatalysis through electric field models and microkinetic volcanoes
This perspective highlights advances in capturing pH-dependent surface structures, reactivity, and mechanisms via electric field-based methods.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA06105A

Reducibility, adsorption energies, surface acidity – fundamental material properties for fast oxygen exchange
Combining a comprehensive discussion of literature with new mechanistic insights, we derive two fundamental design principles for material systems with optimal oxygen exchange kinetics: a shallow O 2p band center and a low work function.
J. Mater. Chem. A, 2025,13, 29885-29899
https://doi.org/10.1039/D5TA05637C
Electrochemical impedance spectroscopy measurements of solid oxide cells: beyond open circuit voltage conditions
This work emphasizes the importance of performing electrochemical impedance spectroscopy analyses in loading mode rather than under open circuit voltage conditions.
J. Mater. Chem. A, 2025,13, 28845-28873
https://doi.org/10.1039/D5TA04017E

Tribocatalysis: a successful marriage of triboelectricity and heterogeneous catalysis
We discuss how tribocatalysis utilizes friction-generated charges to drive chemical transformations. The proposed mechanistic understanding, catalyst design, and future research directions are examined.
J. Mater. Chem. A, 2025,13, 27925-27946
https://doi.org/10.1039/D5TA04021C
Disorder by design: high-entropy oxides as next generation thermoelectric materials
Entropy-engineered oxides for thermoelectric energy.
J. Mater. Chem. A, 2025,13, 27050-27068
https://doi.org/10.1039/D5TA02713F
Beyond traditional TOF: unveiling the pitfalls in electrocatalytic active site determination
TOF reflects intrinsic catalytic activity by measuring per-site efficiency, unlike current density. Accurate TOF estimation requires identifying true active sites and RDS, enabling rational design of efficient electrocatalysts for sustainable water splitting.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04810A
Repurposing PVA-based slime to address electrolyte challenges in portable electrochemical devices
PVA-based slime is an unexplored, cost-effective, and spill-proof alternative to conventional electrolytes. Its inherent ionic conductivity makes it a promising electrolyte for portable electrochemical surface-monitoring probes.
J. Mater. Chem. A, 2025,13, 26202-26214
https://doi.org/10.1039/D5TA03449C
Stabilizing ultrafine intermetallics on carbon supports: from structural design to catalytic applications
Ultrafine intermetallics (<5 nm) offer unique catalytic properties but face sintering challenges. We highlight carbon-supported synthesis strategies for precise control, focusing on electrocatalytic applications and future directions.
J. Mater. Chem. A, 2025,13, 26186-26201
https://doi.org/10.1039/D5TA04405G
Ordered energy conversion systems inspired from the biological world
In addressing the urgent challenges facing the energy industry, this perspective emphasizes the importance of offering efficient, clean and low-carbon ordered energy conversion systems by integrating biology and engineering.
J. Mater. Chem. A, 2025,13, 24416-24434
https://doi.org/10.1039/D5TA03826J

On the use of bioprecursors for sustainable silicon-based anodes for Li-ion batteries
Plants and protists: promising sources for Si-based Li-ion battery anodes.
J. Mater. Chem. A, 2025,13, 21421-21435
https://doi.org/10.1039/D5TA02555A
How common is it to get an OER overpotential that is <250 mV?
This work raises concerns about the unintentional mistakes made by researchers developing OER electrocatalysts by overlooking the fundamentals.
J. Mater. Chem. A, 2025,13, 21436-21452
https://doi.org/10.1039/D5TA00009B
Unveiling the significance of working electrode substrates in electrocatalytic water splitting for sustainable hydrogen energy production
This perspective highlights how electrode substrate choice critically affects electrocatalyst performance in water splitting, guiding researchers to design better catalysts by leveraging each substrate’s unique properties.
J. Mater. Chem. A, 2025,13, 19252-19281
https://doi.org/10.1039/D5TA02980E
Recent advancements in metal–organic frameworks (MOFs) for flexible supercapacitors aimed at wearable technology
Flexible supercapacitors have made significant progress, as they can be integral to the wearable technology field due to their unique ability to allow seamless movement for the wearer.
J. Mater. Chem. A, 2025,13, 19236-19251
https://doi.org/10.1039/D5TA01159K
Advances and industrialization of LiFePO4 cathodes in electric vehicles: challenges, innovations, and future directions
Evolution, research focus, industrialization and recovery techniques of LiFePO4 cathodes are reviewed, highlighting their critical role in meeting energy demands, especially in EVs.
J. Mater. Chem. A, 2025,13, 17271-17283
https://doi.org/10.1039/D5TA00166H
From lab to market: the future of zinc–air batteries powered by MOF/MXene hybrids
Zinc–air batteries (ZABs) stand at the forefront of energy storage technologies. However, challenges like slow kinetics and low rechargeability persist. MOF–MXene hybrids enhance performance, enabling sustainable ZAB technology.
J. Mater. Chem. A, 2025,13, 12855-12890
https://doi.org/10.1039/D5TA01344E
Sulfur element achieves rapid and stable migration of Li+ in oxide cathode materials
Higher energy density can be obtained by increasing the charging cut-off voltage of Ni-rich materials to meet the range requirements of electric vehicles.
J. Mater. Chem. A, 2025,13, 9039-9048
https://doi.org/10.1039/D4TA09238D

Capacity-weighted figures-of-merit for battery transport metrics
Fast-charging materials are necessary for a battery-centric future. Ionic and electronic transport crucially determine performance where their capacity-weighted figures-of-merit account for performance across all states-of-charge.
J. Mater. Chem. A, 2025,13, 6314-6324
https://doi.org/10.1039/D4TA06041E
Recent advances in characterization of rechargeable battery materials via scanning probe microscopy
Scanning probe microscopy can be used to obtain topographical, mechanical, electrical, and electrochemical information on a wide range of materials in a variety of environments, including in situ and operando studies for rechargeable battery systems.
J. Mater. Chem. A, 2025,13, 5561-5581
https://doi.org/10.1039/D4TA05975A
Sorbent-based atmospheric water harvesting: engineering challenges from the process to molecular scale
Atmospheric water harvesting is an emerging technique that can potentially increase water access to water-constrained communities.
J. Mater. Chem. A, 2025,13, 4838-4850
https://doi.org/10.1039/D4TA06883A
Recent advances in nickel-based anodes for anion-exchange membrane water electrolyzers
This review sheds light on the developments made in the affordable Ni-based oxygen evolution catalysts and their potential application in anion-exchange membrane water electrolyzers (AEMWEs) for green hydrogen production.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA05931C
Atomic-level environment engineering in carbon-based single-atom catalysts: a review of theoretical insights for hydrogen evolution and triiodide reduction
Five microenvironment engineering strategies are proposed to modulate single-atom active sites, integrating computational catalysis, functional materials design, and sustainable energy applications to drive interdisciplinary advances.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA05551B
Humidity stability of halide solid-state electrolytes
This review focuses on the humidity stability of halide solid-state electrolytes, including the root causes, characterization methods and mitigation strategies for humidity instability, as well as key challenges and future research directions.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA06216K
Engineering core–sheath phase change fibers for thermal energy storage: fundamentals, fabrication, and smart applications
Core–sheath phase change fibers provide an innovative strategy for precise thermal regulation, scalable PCM encapsulation, and multifunctional integration, offering scalable routes toward advanced thermal management and sustainable energy systems.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA06026E

Strategies for performance and stability advancement in multicomponent perovskite photovoltaics
State-of-the-art strategies adopted for the improvement of photovoltaic performance and stability in multi-component perovskite materials and devices.
J. Mater. Chem. A, 2025,13, 32964-33011
https://doi.org/10.1039/D5TA04375A

Navigating ionic conductivity in MOF electrolytes: addressing measurement pitfalls and performance limits
Schematic of a solid-state battery with a MOF-based electrolyte, where Li+ ions migrate through the porous framework, facilitating ionic conduction between the cathode and anode.
J. Mater. Chem. A, 2025,13, 33012-33033
https://doi.org/10.1039/D5TA04415D
Spin and ferroelectric-driven photocatalysts for efficient CO2 reduction: material design and future perspectives
This review summarizes recent advances in spin- and ferroelectric-driven photocatalysts, highlighting material design strategies that control electron polarization to promote charge separation and boost CO2 photoreduction efficiency.
J. Mater. Chem. A, 2025,13, 33057-33079
https://doi.org/10.1039/D5TA04789G
Bridging lab-to-fab gaps: recent advances in the reproducibility of organic solar cells
This review comprehensively summarizes the recent advances in OSC reproducibility of organic solar cells from material synthesis, film preparation, and interfacial & electrode, which would provide significant insights into large-scale fabrication.
J. Mater. Chem. A, 2025,13, 32946-32963
https://doi.org/10.1039/D5TA05788D
Recent advances in the application of magnetron sputtering for lithium metal batteries
The present review systematically outlines recent progress in utilizing magnetron sputtering for lithium metal batteries, highlighting emerging coating strategies such as target design and their corresponding characterization methodologies.
J. Mater. Chem. A, 2025,13, 33104-33135
https://doi.org/10.1039/D5TA03766B

Emerging innovations in polymeric hollow fiber membranes for sustainable natural gas valorization
This review highlights advanced hollow fiber membranes for natural gas processing, focusing on innovative materials and fabrication techniques that overcome permeance-selectivity trade-offs while addressing plasticization and aging challenges.
J. Mater. Chem. A, 2025,13, 33080-33103
https://doi.org/10.1039/D5TA04814A
A newly synthesized 2D polyaramid: structure, properties, and applications in energy storage, electrocatalysis, and sensing
This review presents a comprehensive discussion of the multifunctional applications of 2DPA.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA03830H
Recent advances in bio-inspired radiative cooling film designs for sustainable building applications
This review examines the operational mechanisms of radiative cooling, identifies limitations of conventional film materials, and evaluates recent progress in bio-inspired design strategies for radiative cooling films.
J. Mater. Chem. A, 2025,13, 33034-33056
https://doi.org/10.1039/D5TA04553C
Beyond graphene: a review of graphene's lesser-known yne relatives and their energy applications
The experimental advances and computational predictions of the yne relatives of graphene, graphyne (GY), graphdiyne (GDY), graphtriyne (GTY) and graphtetrayne (GT4Y), in energy and environmental applications are reviewed.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04704H
Molten salt synthesis of low-dimensional nanostructured perovskite oxide electrocatalysts for the oxygen evolution reaction: a review
This work summarizes research progress in molten salt synthesis of low dimensional nanostructured perovskite oxide electrocatalysts for the oxygen evolution reaction, which covers their synthesis, structural characterization and applications.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04598C
Low-cost polyanion cathodes for sodium ion batteries: challenges, strategies, and progress
This review focuses on the modification measures of polyanionic cathode materials, pays attention to their improvement effect on the performance of active materials, and discusses the modification mechanism and the latest development trend.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA05622E
Advances in solvent-free syntheses of covalent organic frameworks towards catalysis and battery applications
This review provides an introduction to the recent progress of solvent-free syntheses of COFs, summarizes their preparation methods, unique advantages and applications in catalysis and batteries and discusses the opportunities and challenges.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA05581D

Low-cost, large-area carbon electrode perovskite solar cells
The application of carbon electrodes, as an interface and a terminal electrode in carbon-based perovskite solar cells (C-PSCs).
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA05091J
Layered double hydroxide-based catalysts for seawater electrolysis at industrial current densities: advances and perspectives
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA06646H
Non-free water dominated electrolyte architectures for zinc-based batteries: toward sustainable long-life zinc-based energy storage solutions
Non-free water dominated electrolyte architecture is reviewed based on a new perspective of different forms of electrolytes, mainly including lean-water liquid electrolytes, gelatinized electrolytes, and solidified electrolytes.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04836B
Recent progress on ZnIn2S4 -based composite photocatalyst for photocatalytic hydrogen production coupling organic synthesis
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA06861D
Leveraging the Ingenuity of Carbon Nanomaterials towards Water Quality Amelioration
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA05332C
Awakening the Substrate: Design of Foam Metal Electrodes for Water Electrolysis
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA07016C
Advances in microwave-absorbing materials: from fundamentals to emerging technologies
Advancement of different microwave absorbing materials and their absorption mechanism for emerging technologies.
J. Mater. Chem. A, 2025,13, 31869-31920
https://doi.org/10.1039/D5TA03936C
Porphyrin-based heterojunction photocatalysts: design principles and applications in solar-to-chemical energy conversion
As global climate change and energy crises continue to escalate, the development of efficient solar energy conversion technologies has become imperative for addressing pressing environmental and energy-related challenges.
J. Mater. Chem. A, 2025,13, 32030-32055
https://doi.org/10.1039/D5TA05146K
CO2 utilization in energy storage and conversion
This review explores four emerging CO2-based energy technologies that utilize CO2 as an active energy carrier, highlighting its roles, challenges, and future strategies in sustainable energy conversion and storage.
J. Mater. Chem. A, 2025,13, 32004-32029
https://doi.org/10.1039/D5TA04747A
Photocatalytic synergies: mechanisms, enhancement strategies, and applications
Synergistic multi-field photocatalysis—integrating photo-piezoelectric, photothermal, photomagnetic, and other effects—uses in situ characterization and ab initio methods to boost charge separation and reaction kinetics for environmental/energy use.
J. Mater. Chem. A, 2025,13, 31954-31977
https://doi.org/10.1039/D5TA05414A
AFP-based anti-icing coatings: present challenges and future opportunities
AFP-based anti-icing coatings prevent surface icing through dual mechanisms: dynamic repulsion of impacting water droplets and significant suppression of ice-adhesion forces.
J. Mater. Chem. A, 2025,13, 32104-32110
https://doi.org/10.1039/D5TA03663A
Innovative conversion electrode materials and electrolyte strategies in aqueous zinc–S/Se batteries for advanced energy storage
This review summarizes recent strategies to enhance AZSBs and AZSeBs, including cathode and electrolyte optimization, advanced characterization, and reaction mechanism studies, while highlighting current challenges and future development directions.
J. Mater. Chem. A, 2025,13, 31921-31953
https://doi.org/10.1039/D5TA04605J
Recent advances in functional energy materials for microbial fuel cells: progress, challenges, and future perspectives
Microbial fuel cells (MFCs) are a promising sustainable technology for addressing global energy shortages and environmental pollution, attracting increasing research interest in recent years.
J. Mater. Chem. A, 2025,13, 32056-32103
https://doi.org/10.1039/D5TA04072H
Enhancing lithium–sulfur battery performance with dual-atom catalysts: a synergistic approach
This study explores advancements of Li–S batteries with dual atom catalysts (DACs), focusing on support morphology, DAC atomic coordination, battery performance, and simulations of both electronic structure and atomistic mechanisms.
J. Mater. Chem. A, 2025,13, 31829-31868
https://doi.org/10.1039/D5TA03508B
Biomass-based separators for aqueous zinc-ion batteries: advantages, strategies, and perspectives
A comprehensive review of the design, preparation, and performance of biomass-based separators in ZIBs, highlighting their roles in enhancing safety, ion transport, and dendrite suppression, along with current challenges and future prospects.
J. Mater. Chem. A, 2025,13, 31978-32003
https://doi.org/10.1039/D5TA05279C
Advances in reversible protonic ceramic electrochemical cells operated below 723 K: theoretical insights and experimental developments
Lowering the operating temperature of reversible protonic ceramic electrochemical cells below 723 K can not only prevent component degradation and lower system costs but also enhance the overall efficiency.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04354A

Carbon-based materials for more reliable solid-state Li batteries
The multi-functional features of carbon-based materials have shown significant potential in addressing the challenges associated with advanced solid-state lithium batteries.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04266F
Beyond activity: from machine learning screening to stability decoding on the study of self-supported metal phosphides in alkaline hydrogen evolution reaction
This review summarizes the research advancements of self-supported TMPs in alkaline HER, including machine learning-assisted screening, strategies for activity enhancement, and factors influencing stability along with improvement methodologies.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04915F
Recent advances in anion-exchange membranes for electrolyzers, fuel cells and redox-flow batteries
This review highlights the recent progress in the development of anion-exchange membranes for affordable electrochemical energy devices-electrolyzers, fuel cells, and vanadium redox-flow batteries.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA05392G
Engineering Asymmetric MOF Composites toward High-Efficiency Catalytic Reactions
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA07121F
Single-atom alloys for photocatalytic applications: material innovation and light-driven reactivity
Single-atom alloys are presented through synthesis, mechanisms, and photocatalytic applications, highlighting atomic-level and alloying effects in light-driven catalysis.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04700E
Opaque, transparent, and colored low-emissivity materials for mid-infrared thermal management
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA05910K
Emerging multimetal LMFP-based cathodes for lithium-ion batteries: a review
Multimetal LMFP cathodes offer enhanced conductivity, stability, and energy density for lithium-ion batteries. This review outlines doping, structural integration, and entropy strategies to overcome key limitations and guide future developments.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA03194J
Defect structures in supercapacitor electrodes: non-oxide 2D materials and metal oxides
This review highlights how crystallographic and interfacial defects control charge storage in supercapacitors by modulating electronic structure, ion transport, and redox kinetics, ultimately shaping capacitive behavior and stability.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04716A
Interface engineering in polymer thermoelectric composites: harnessing energy-filtering effects to overcome the Seebeck-conductivity trade-off
A systematic review of energy filtering (EF) engineering in polymer-based TE composites is presented. The effect of EF on ionic organic films, organic–inorganic composites, MXene-based hybrids and aerogel composites is analysed.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA05957G
Polymorphs of VO2 and their MXene-based hybrid materials for energy storage applications
The well-defined crystal structure of VO2 polymorphs have gained significant attention as a promising electrode material. Furthermore, its composites with MXenes are summarized for efficient energy storage applications.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04219D
Practice and tactics in the construction of novel degradable plastics at polymer and molecular levels
The technology for achieving controlled degradation of plastics at the polymer and molecular levels has been comprehensively reviewed.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04817F
Lithium based battery systems: technological and environmental challenges and opportunities
The United Nations has prioritized decarbonization and reducing greenhouse gas emissions, leading nations to adopt policies for increased renewable energy use. Lithium-ion batteries are key to this shift, though they present challenges to overcome.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA05419B
A review of the design, applications, and mechanisms of electrically assisted reverse osmosis and nanofiltration processes
The application of electricity to RO and NF, through the superimposition of external electric fields (ENF, ERO) or the integration of electrically conductive membranes (ECMs), represents a promising approach to outperform conventional processes.
J. Mater. Chem. A, 2025,13, 30843-30869
https://doi.org/10.1039/D5TA03831F
Recent advances of photothermal technology in CO2 capture and methanation
Overview of the mechanisms and categories of photothermal materials for photothermal CO2 capture and methanation.
J. Mater. Chem. A, 2025,13, 30823-30842
https://doi.org/10.1039/D5TA03108G
Recent advances in liquid metals as electrodes, electrolytes and interface stabilizers for lithium batteries and beyond
This review presents the recent advances in liquid metals (LMs) as key electrodes, electrolyte materials, and interface stabilizers for lithium and other batteries. The remaining challenges and future opportunities are also illustrated.
J. Mater. Chem. A, 2025,13, 30796-30822
https://doi.org/10.1039/D5TA04996B
Recent advances in metal-based Janus nanomaterials: synthesis and electrocatalytic applications
This review provides the recent progress on the synthesis and electrocatalytic applications of novel Janus metal-based nanomaterials.
J. Mater. Chem. A, 2025,13, 30906-30928
https://doi.org/10.1039/D5TA04223B

Reasonable active site design for promoting water dissociation and carbon monoxide activation in a low-temperature water-gas shift reaction
This work considers different catalyst design ideas for enhancing the low-temperature WGSR performance based on the combination of two half-reactions, which occur on different active sites with different optimizing strategies.
J. Mater. Chem. A, 2025,13, 30755-30767
https://doi.org/10.1039/D5TA02030A
About this collection
This collection contains recent Review-type articles published by Journal of Materials Chemistry A, the home for high impact applications, properties and synthesis of exciting new materials for energy and sustainability.
New articles will be added to this collection as soon as possible after publication.