Issue 29, 2020
From the journal:

Dalton Transactions

Radii-dependent self-assembly of chiral lanthanide complexes: synthesis, chirality, and single-molecule magnet behavior†

Ge Li,a   Xiaoxi Zhao,a   Qingxin Han,b   Li Wang*c  and  Weisheng Liu ORCID logo *a  

* Corresponding authors

a Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province and State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, P. R. China
E-mail: liuws@lzu.edu.cn

b College of Bioresources Chemistry and Materials Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China

c College of Chemistry and Chemical Engineering, Xi'an Shiyou University, Xi'an 710065, P.R. China
E-mail: lwang2018@xsyu.edu.cn

Abstract

A pair of 3-methoxysalicylhydrazone-based homochiral ligands constructed chiral trinuclear and pentanuclear complexes with LaIII and DyIII ions, respectively, which indicates that the radii controlled the self-assembled structures. Chiral transfer during the self-assembly processes was confirmed by crystal structure analysis and CD spectroscopy. Then, magnetic investigations demonstrated that the chiral Dy5 complexes exhibited typical single-molecule magnet behavior.

Graphical abstract: Radii-dependent self-assembly of chiral lanthanide complexes: synthesis, chirality, and single-molecule magnet behavior

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D0DT01711F
Article type
Paper
Submitted
12 Mei 2020
Accepted
01 Jul 2020
First published
07 Jul 2020

Dalton Trans., 2020,49, 10120-10126

Permissions

Request permissions

Radii-dependent self-assembly of chiral lanthanide complexes: synthesis, chirality, and single-molecule magnet behavior

G. Li, X. Zhao, Q. Han, L. Wang and W. Liu, Dalton Trans., 2020, 49, 10120 DOI: 10.1039/D0DT01711F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements