Issue 40, 2009

Iridium-catalyzed enantioselective hydrogenation of vinyl boronates

Abstract

The first Ir-catalyzed asymmetric hydrogenations of vinyl boronates have been performed using low catalyst loadings (0.5 mol%) and pressure (as low as 1 bar). Good selectivities (76–98% ee) were obtained for a range of substrates.

Graphical abstract: Iridium-catalyzed enantioselective hydrogenation of vinyl boronates

Article information

Article type
Communication
Submitted
25 Jun 2009
Accepted
24 Ago 2009
First published
15 Sep 2009

Chem. Commun., 2009, 5996-5998

Iridium-catalyzed enantioselective hydrogenation of vinyl boronates

A. Paptchikhine, P. Cheruku, M. Engman and P. G. Andersson, Chem. Commun., 2009, 5996 DOI: 10.1039/B912590F

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