Issue 40, 2009
From the journal:

Chemical Communications

Ultra-short contact time conversion of chloromethane to olefins over pre-coked SAPO-34: direct insight into the primary conversion with coke deposition†

Yingxu Wei,a   Dazhi Zhang,a   Fuxiang Chang,a   Qinghua Xia,ad   Bao-Lian Su*abc  and  Zhongmin Liu*a  

* Corresponding authors

a Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, P. O. Box 110, 116023 Dalian, P. R. China
E-mail: liuzm@dicp.ac.cn
Fax: +86-411-84691570
Tel: +86-411-84685510

b Laboratory of Inorganic Materials Chemistry (CMI), The University of Namur (FUNDP), B-5000 Namur, Belgium
E-mail: bao-lian.su@fundp.ac.be
Fax: +32-81725414
Tel: +32-81724531

c State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 430070, Wuhan, Hubei, P. R. China

d Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Hubei University, 430062 Wuhan, P. R. China

Abstract

Hydrocarbon species trapped in the catalyst that work as the reaction center and govern the conversion and product selectivity of chloromethane transformation were revealed by a very efficient home-made ultra-short contact time pulse reaction system over pre-coked SAPO-34.

Graphical abstract: Ultra-short contact time conversion of chloromethane to olefins over pre-coked SAPO-34: direct insight into the primary conversion with coke deposition

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Article information

DOI
https://doi.org/10.1039/B909218H
Article type
Communication
Submitted
11 May 2009
Accepted
10 Sep 2009
First published
18 Sep 2009

Chem. Commun., 2009, 5999-6001

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Ultra-short contact time conversion of chloromethane to olefins over pre-coked SAPO-34: direct insight into the primary conversion with coke deposition

Y. Wei, D. Zhang, F. Chang, Q. Xia, B. Su and Z. Liu, Chem. Commun., 2009, 5999 DOI: 10.1039/B909218H

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