We report the synthesis, spectroscopic analyses and solid-state structural evidence of an unprecedented positional isomer of aromatic [18] N-confused corrole exhibiting vis-NIR absorption. The copper metalation led to an organo-copper(III) complex with preserved aromaticity.
H. Rath, A. Panua, G. Velmurugan and P. Comba, Chem. Commun., 2025, Accepted Manuscript , DOI: 10.1039/D5CC05372B
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