An [FeIII8] molecular oxyhydroxide

Daniel J. Cutler; Marco Coletta; Mukesh K. Singh; Angelos B. Canaj; Laura J. McCormick; Simon J. Coles; Jürgen Schnack; Euan K. Brechin

doi:10.1039/D2DT01477G

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An [Fe^III₈] molecular oxyhydroxide†

Daniel J. Cutler,

^a Marco Coletta,

^a Mukesh K. Singh,

^a Angelos B. Canaj,

^a Laura J. McCormick,

^b Simon J. Coles,

^b Jürgen Schnack

*^c and Euan K. Brechin

*^a

Author affiliations

* Corresponding authors

^a EaStCHEM School of Chemistry, The University of Edinburgh, David Brewster Road, Edinburgh, Scotland, UK
E-mail: E.Brechin@ed.ac.uk

^b EPSRC National Crystallography Service, School of Chemistry, University of Southampton, Highfield, Southampton, UK

^c Universitat Bielefeld, Postfach 100131, D-33501 Bielefeld, Germany
E-mail: jschnack@uni-bielefeld.de

Abstract

An [Fe^III₈] hexagonal bipyramid displays antiferromagnetic exchange between the two capping tetrahedral ions and the six ring octahedral ions resulting in a spin ground state of S = 10.

This article is part of the themed collection: Open Access in Dalton Transactions

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Article information

DOI: https://doi.org/10.1039/D2DT01477G
Article type: Communication
Submitted: 12 Mei 2022
Accepted: 18 Mei 2022
First published: 18 Mei 2022
This article is Open Access

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Dalton Trans., 2022,51, 8945-8948

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An [Fe^III₈] molecular oxyhydroxide

D. J. Cutler, M. Coletta, M. K. Singh, A. B. Canaj, L. J. McCormick, S. J. Coles, J. Schnack and E. K. Brechin, Dalton Trans., 2022, 51, 8945 DOI: 10.1039/D2DT01477G

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