Issue 23, 2022
From the journal:

Dalton Transactions

Cerium-oxo clusters for photocatalytic aerobic oxygenation of sulfides to sulfoxides†

Xinjie Lv,‡a   Xiao-li Zhao, ORCID logo ‡b   Qixin Zhao,a   Qi Zheng ORCID logo *c  and  Weimin Xuan ORCID logo *a  

* Corresponding authors

a College of Chemistry, Chemical Engineering and Biotechnology & State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, Shanghai 201620, P. R. China
E-mail: weiminxuan@dhu.edu.cn

b Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663 North Zhongshan Road, Shanghai 200062, P. R. China

c State Key Laboratory for Modification of Chemical Fibers and Polymer Materials & College of Materials Science and Engineering, Donghua University, Shanghai 201620, P. R. China
E-mail: qi.zheng@dhu.edu.cn

Abstract

Two cerium-oxo clusters (COCs) 1 and 2 are constructed by self-assembly of cerium ions and carboxylate ligands. Both clusters feature spherical structures resembling the key moiety of fluorite phase CeO2, and 1 exhibits high activity and selectivity for the photocatalytic aerobic oxygenation of sulfides to sulfoxides based on the switch between the Ce(IV/III) redox couple.

Graphical abstract: Cerium-oxo clusters for photocatalytic aerobic oxygenation of sulfides to sulfoxides

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Article information

DOI
https://doi.org/10.1039/D2DT00856D
Article type
Communication
Submitted
19 Mar 2022
Accepted
23 May 2022
First published
25 May 2022

Dalton Trans., 2022,51, 8949-8954

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Cerium-oxo clusters for photocatalytic aerobic oxygenation of sulfides to sulfoxides

X. Lv, X. Zhao, Q. Zhao, Q. Zheng and W. Xuan, Dalton Trans., 2022, 51, 8949 DOI: 10.1039/D2DT00856D

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