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The formation of interlocked lanthanide-based catenanes using Eu(III)-directed synthesis is described (catenation being achieved via a ring-closing metathesis reaction); the self-assembly formation of the supramolecular structures was analysed by HRMS, NMR and luminescent spectroscopies.

Graphical abstract: Self-assembly formation of mechanically interlocked [2]- and [3]catenanes using lanthanide ion [Eu(iii)] templation and ring closing metathesis reactions

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