Issue 22, 2017

C–H functionalization by high-valent Cp*Co(iii) catalysis

Abstract

Significant progress has been accomplished in directed C–H functionalization through the use of earth-abundant and inexpensive first-row transition metals. Among these base metals, Co is especially attractive in view of its versatile applications in C–H functionalization, in both low- and high-valent states. In this vein, catalytic Co(III) species can be generated from the dissociation of a Cp*Co(III) catalyst or through the oxidation of a low-valent cobalt catalyst in the presence of an oxidant. In this feature article, we will discuss the breakthroughs in Cp*Co(III)-promoted C–H functionalization. In this field, C(sp2)–H functionalization has been extensively studied and developed. In contrast, few C(sp3)–H functionalization reactions have been reported.

Graphical abstract: C–H functionalization by high-valent Cp*Co(iii) catalysis

Article information

Article type
Feature Article
Submitted
05 Tsh 2016
Accepted
22 Kol 2017
First published
23 Kol 2017

Chem. Commun., 2017,53, 3165-3180

C–H functionalization by high-valent Cp*Co(III) catalysis

S. Wang, S. Chen and X. Yu, Chem. Commun., 2017, 53, 3165 DOI: 10.1039/C6CC09651D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements