Issue 5, 2014

Visible-light photocatalytic oxidation of 1,3-dicarbonyl compounds and carbon–carbon bond formation

Abstract

Visible-light photocatalytic oxidation of 1,3-dicarbonyl compounds, using Ru(bpy)3Cl2 as a photocatalyst and combining molecular oxygen and triphenylcarbenium as a new sacrificial acceptor, has been developed for carbon–carbon bond formation giving access to dimerization, allylation and polycyclization products.

Graphical abstract: Visible-light photocatalytic oxidation of 1,3-dicarbonyl compounds and carbon–carbon bond formation

Supplementary files

Article information

Article type
Research Article
Submitted
13 mar 2014
Accepted
29 apr 2014
First published
30 apr 2014

Org. Chem. Front., 2014,1, 551-555

Visible-light photocatalytic oxidation of 1,3-dicarbonyl compounds and carbon–carbon bond formation

M. Daniel, L. Fensterbank, J. Goddard and C. Ollivier, Org. Chem. Front., 2014, 1, 551 DOI: 10.1039/C4QO00071D

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