Issue 5, 2014
From the journal:

Organic Chemistry Frontiers

Palladium-catalyzed direct C–H allylation of arenes without directing groups†

Cheng-Hao Yinga  and  Wei-Liang Duan*a  

* Corresponding authors

a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China
E-mail: wlduan@mail.sioc.ac.cn
Fax: (+86)-21-6416-6128
Tel: (+86)-21-5492-5203

Abstract

A palladium-catalyzed direct C–H allylation of simple arenes without directing groups was developed for allyl arene synthesis. The use of bidentate monoanionic nitrogen ligands enabled the progress of initial C–H activation of arenes, as well as the subsequent insertion and β-OAc elimination.

Graphical abstract: Palladium-catalyzed direct C–H allylation of arenes without directing groups

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Article information

DOI
https://doi.org/10.1039/C4QO00097H
Article type
Research Article
Submitted
29 Mar 2014
Accepted
27 Apr 2014
First published
28 Apr 2014

Org. Chem. Front., 2014,1, 546-550

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Palladium-catalyzed direct C–H allylation of arenes without directing groups

C. Ying and W. Duan, Org. Chem. Front., 2014, 1, 546 DOI: 10.1039/C4QO00097H

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