Issue 6, 2022

[closo-B10H8-1,10-(COOH)2]2−: a building block for functional materials?

Abstract

[closo-B10H8-1,10-(COOH)2]2− was obtained in five steps and 40% overall yield from [closo-B10H10]2−. It can be converted to [closo-B10H8-1,10-(CO)2] and subsequently to carbonium ylides [closo-B10H8-1-COOH-10-(C(NRCH2)2)]. The diacid, its derivatives, and di-ylide [closo-B10H8-1,10-(C(NHMe)2)2] are characterized by spectroscopic and single crystal XRD methods augmented with DFT results.

Graphical abstract: [closo-B10H8-1,10-(COOH)2]2−: a building block for functional materials?

Supplementary files

Article information

Article type
Communication
Submitted
17 nov 2021
Accepted
15 dec 2021
First published
15 dec 2021

Chem. Commun., 2022,58, 851-854

Author version available

[closo-B10H8-1,10-(COOH)2]2−: a building block for functional materials?

S. Kapuściński, O. Hietsoi, A. Pietrzak, A. C. Friedli and P. Kaszyński, Chem. Commun., 2022, 58, 851 DOI: 10.1039/D1CC06485A

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