Open metal sites dangled on cobalt trigonal prismatic clusters within porous MOF for CO2 capture

Wen-Yang Gao; Sathvik Palakurty; Lukasz Wojtas; Yu-Sheng Chen; Shengqian Ma

doi:10.1039/C4QI00240G

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Open metal sites dangled on cobalt trigonal prismatic clusters within porous MOF for CO₂ capture†

Wen-Yang Gao,^a Sathvik Palakurty,^a Lukasz Wojtas,^a Yu-Sheng Chen^b and Shengqian Ma*^a

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* Corresponding authors

^a Department of Chemistry, University of South Florida, 4202 E. Flower Avenue, Tampa, Florida 33620, USA
E-mail: sqma@usf.edu
Fax: +1-813-974-3203
Tel: +1-813-974-5217

^b ChemMatCARS, Center for Advanced Radiation Sources, The University of Chicago, 9700 S. Cass Avenue, Argonne, Illinois 60439, USA

Abstract

Open metal sites are devised to dangle on cobalt trigonal prismatic secondary building units (SBUs) of a porous MOF, when a rigid octacarboxylate ligand, 1,3,6,8-tetra(3,5-dicarboxylphenyl)pyrene, assembled with Co(NO₃)₂ under solvothermal conditions. The functional role of dangled open metal sites is exploited for CO₂ capture studies.

This article is part of the themed collection: Crystal engineering for molecular materials

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Article information

DOI: https://doi.org/10.1039/C4QI00240G
Article type: Research Article
Submitted: 28 dec 2014
Accepted: 23 jan 2015
First published: 26 jan 2015

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Inorg. Chem. Front., 2015,2, 369-372

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Open metal sites dangled on cobalt trigonal prismatic clusters within porous MOF for CO₂ capture

W. Gao, S. Palakurty, L. Wojtas, Y. Chen and S. Ma, Inorg. Chem. Front., 2015, 2, 369 DOI: 10.1039/C4QI00240G

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