Issue 6, 2014

Iridium(iii) dipyridylamine complexes: synthesis, characterization and catalytic activities in photoredox reactions

Abstract

Two new series of cyclometalated iridium(III) complexes bearing a dipyridylamine as the N^N ligand have been prepared and fully characterized. After investigation of their photophysical properties, their catalytic activities have been evaluated in a model photoredox reaction and compared with the commercially available [Ir(ppy)2(dtbbpy)][PF6] complex.

Graphical abstract: Iridium(iii) dipyridylamine complexes: synthesis, characterization and catalytic activities in photoredox reactions

Supplementary files

Article information

Article type
Research Article
Submitted
28 feb 2014
Accepted
28 apr 2014
First published
29 apr 2014

Org. Chem. Front., 2014,1, 639-644

Iridium(III) dipyridylamine complexes: synthesis, characterization and catalytic activities in photoredox reactions

E. Sauvageot, R. Marion, F. Sguerra, A. Grimault, R. Daniellou, M. Hamel, S. Gaillard and J. Renaud, Org. Chem. Front., 2014, 1, 639 DOI: 10.1039/C4QO00059E

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