This website uses cookies to give you the best user experience. If you continue without changing your settings we'll assume you are happy to receive all RSC cookies. You can change your cookie settings by navigating to our Privacy and Cookies page and following the instructions. These instructions are also obtainable from the privacy link at the bottom of any RSC page.
Lite Version|Standard version
Home > Organic & Biomolecular ... >
To gain access to this content please
Log in via your home Institution.
Log in with your member or subscriber username and password.
Download


Buy PDF Add PDF to Basket (£42,50*)
*Exclusive of taxes
This article contains 4 page(s)
Abstract | Cited by

A very effective spirocyclization procedure for installing nucleophiles (Nu = N3, NO2, SCN, SO2Tol, and halogens) viaiodonium(III) salts has been developed using the combination of iodoarene and mCPBA. The high-yielding syntheses of the cyclohexadienone-type spirocyclic compounds 2 having varied functionalities in the skeletons have been achieved from the aryl alkynes 1 with the optimized bis(iodoarene) 3h.

Graphical abstract: New synthesis of spirocycles by utilizing in situ forming hypervalent iodine species

Page: ^ Top


Enter Keywords, author, title,reference, or DOI
Log in | Register