Issue 20, 2011
From the journal:

Organic & Biomolecular Chemistry

Palladium-catalyzed C–H acetoxylation of 2-methoxyimino-2-aryl-acetates and acetamides†

Liang Wang,a   Xu-Dong Xia,a   Wei Guo,a   Jia-Rong Chena  and  Wen-Jing Xiao*a  

* Corresponding authors

a Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei, China
E-mail: wxiao@mail.ccnu.edu.cn
Fax: +86 27 67862041
Tel: +86 27 6786 2041

Abstract

Palladium-catalyzed C–H acetoxylation reactions of 2-methoxyimino-2-aryl-acetates and acetamides have been developed. These transformations feature excellent regioselectivity, wide substrate scope, and moderate to good yields. The product can be easily converted into naturally unprecedented α-amino acids in excellent yields.

Graphical abstract: Palladium-catalyzed C–H acetoxylation of 2-methoxyimino-2-aryl-acetates and acetamides

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Article information

DOI
https://doi.org/10.1039/C1OB05887H
Article type
Communication
Submitted
03 Jun 2011
Accepted
28 Jul 2011
First published
29 Jul 2011

Org. Biomol. Chem., 2011,9, 6895-6898

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Palladium-catalyzed C–H acetoxylation of 2-methoxyimino-2-aryl-acetates and acetamides

L. Wang, X. Xia, W. Guo, J. Chen and W. Xiao, Org. Biomol. Chem., 2011, 9, 6895 DOI: 10.1039/C1OB05887H

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