Issue 20, 2019

Visible-light-mediated photoredox decarbonylative Minisci-type alkylation with aldehydes under ambient air conditions

Abstract

Visible-light-induced photoredox decarbonylative C–C bond formation with aldehydes is described for the first time. Minisci-type alkylation reactions of N-heteroarenes proceed smoothly at ambient temperature with air as the sole oxidant. The present sustainable protocol uses readily available organofluorescein as a photocatalyst, cheap and green oxidant and a sustainable power source, thus featuring potential for applications in late-stage modification of valuable molecules.

Graphical abstract: Visible-light-mediated photoredox decarbonylative Minisci-type alkylation with aldehydes under ambient air conditions

Supplementary files

Article information

Article type
Communication
Submitted
26 aug 2019
Accepted
24 sep 2019
First published
24 sep 2019

Green Chem., 2019,21, 5512-5516

Visible-light-mediated photoredox decarbonylative Minisci-type alkylation with aldehydes under ambient air conditions

Z. Wang, X. Ji, J. Zhao and H. Huang, Green Chem., 2019, 21, 5512 DOI: 10.1039/C9GC03008E

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