Issue 91, 2018

Correlating thermochromic and mechanochromic phosphorescence with polymorphs of a complex gold(i) double salt with infinite aurophilicity

Abstract

A complex [Au(NHC)2][Au(C[triple bond, length as m-dash]N)2] double salt exhibits polymorphic crystalline structures with distinct phosphorescence and variations at Au⋯Au distances and ligand–ligand torsion angles. This serves as a model system correlating aurophilicity and low-energy charge-transfer electronic transitions and helps to understand the thermochromism and mechanochromism of the gold(I) complexes.

Graphical abstract: Correlating thermochromic and mechanochromic phosphorescence with polymorphs of a complex gold(i) double salt with infinite aurophilicity

Supplementary files

Article information

Article type
Communication
Submitted
29 jún 2018
Accepted
17 okt 2018
First published
17 okt 2018

Chem. Commun., 2018,54, 12844-12847

Correlating thermochromic and mechanochromic phosphorescence with polymorphs of a complex gold(I) double salt with infinite aurophilicity

Q. Liu, M. Xie, X. Chang, Q. Gao, Y. Chen and W. Lu, Chem. Commun., 2018, 54, 12844 DOI: 10.1039/C8CC05210G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements