[closo-B10H8-1,10-(COOH)2]2−: a building block for functional materials?†
Szymon
Kapuściński, 
ab
Oleksandr
Hietsoi,
a
Anna
Pietrzak,
c
Andrienne C.
Friedli
a
and
Piotr
Kaszyński
*abd
ab
Oleksandr
Hietsoi,
a
Anna
Pietrzak,
c
Andrienne C.
Friedli
a
and
Piotr
Kaszyński
*abd
Abstract
[closo-B10H8-1,10-(COOH)2]2− was obtained in five steps and 40% overall yield from [closo-B10H10]2−. It can be converted to [closo-B10H8-1,10-(CO)2] and subsequently to carbonium ylides [closo-B10H8-1-COOH-10-(C(NRCH2)2)]. The diacid, its derivatives, and di-ylide [closo-B10H8-1,10-(C(NHMe)2)2] are characterized by spectroscopic and single crystal XRD methods augmented with DFT results.
![Graphical abstract: [closo-B10H8-1,10-(COOH)2]2−: a building block for functional materials?](/sk/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=D1CC06485A&imageInfo.ImageIdentifier.Year=2022)
- This article is part of the themed collection: Boron Chemistry in the 21st Century: From Synthetic Curiosities to Functional Molecules
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