Issue 30, 2017

Pd-Catalyzed double N-arylation of primary amines to synthesize phenoxazines and phenothiazines

Abstract

An efficient and versatile Pd-catalyzed tandem C–N bond formation between aryl halides and primary amines is developed. The transformation allows a one-pot synthesis of phenoxazine and phenothiazine derivatives with a broad range of substitution patterns from readily available precursors.

Graphical abstract: Pd-Catalyzed double N-arylation of primary amines to synthesize phenoxazines and phenothiazines

Supplementary files

Article information

Article type
Communication
Submitted
25 июн 2017
Accepted
07 июл 2017
First published
07 июл 2017

Org. Biomol. Chem., 2017,15, 6306-6309

Pd-Catalyzed double N-arylation of primary amines to synthesize phenoxazines and phenothiazines

L. Zhang, X. Huang, S. Zhen, J. Zhao, H. Li, B. Yuan and G. Yang, Org. Biomol. Chem., 2017, 15, 6306 DOI: 10.1039/C7OB01540B

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