‘All three-in-one’: ferromagnetic interactions, single-molecule magnetism and magnetocaloric properties in a new family of [Cu4Ln] (LnIII = Gd, Tb, Dy) clusters

Paul Richardson; Dimitris I. Alexandropoulos; Luís Cunha-Silva; Giulia Lorusso; Marco Evangelisti; Jinkui Tang; Theocharis C. Stamatatos

doi:10.1039/C5QI00146C

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‘All three-in-one’: ferromagnetic interactions, single-molecule magnetism and magnetocaloric properties in a new family of [Cu₄Ln] (Ln^III = Gd, Tb, Dy) clusters†

Paul Richardson,^a Dimitris I. Alexandropoulos,^a Luís Cunha-Silva,^c Giulia Lorusso,^d Marco Evangelisti,^d Jinkui Tang*^b and Theocharis C. Stamatatos*^a

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* Corresponding authors

^a Department of Chemistry, Brock University, St. Catharines, Ontario, L2S3A1, Canada
E-mail: tstamatatos@brocku.ca
Tel: (+1)-905-688-5550 Ext. 3400

^b State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China

^c REQUIMTE/LAQV & Department of Chemistry and Biochemistry, Faculty of Sciences, University of Porto, 4169-007 Porto, Portugal

^d Instituto de Ciencia de Materiales de Aragón (ICMA) and Departamento de Física de la Materia Condensada, CSIC-Universidad de Zaragoza, 50009 Zaragoza, Spain

Abstract

A new family of isomorphous [Cu₄Ln] clusters (Ln^III = Gd, Tb, Dy) with a ‘propeller’-like topology was obtained from the use of naphthalene-2,3-diol in Cu^II/Ln^III chemistry; all complexes are ferromagnetically-coupled and display either magnetocaloric properties or SMM behavior depending on the central Ln ion.

This article is part of the themed collection: Molecular Magnetism themed collection

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Article information

DOI: https://doi.org/10.1039/C5QI00146C
Article type: Research Article
Submitted: 12 ago 2015
Accepted: 08 set 2015
First published: 09 set 2015

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Inorg. Chem. Front., 2015,2, 945-948

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‘All three-in-one’: ferromagnetic interactions, single-molecule magnetism and magnetocaloric properties in a new family of [Cu₄Ln] (Ln^III = Gd, Tb, Dy) clusters

P. Richardson, D. I. Alexandropoulos, L. Cunha-Silva, G. Lorusso, M. Evangelisti, J. Tang and T. C. Stamatatos, Inorg. Chem. Front., 2015, 2, 945 DOI: 10.1039/C5QI00146C

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