Issue 12, 2022

High-performance all-solid-state electrolyte for sodium batteries enabled by the interaction between the anion in salt and Na3SbS4

Abstract

All-solid-state sodium batteries with poly(ethylene oxide) (PEO)-based electrolytes have shown great promise for large-scale energy storage applications. However, the reported PEO-based electrolytes still suffer from a low Na+ transference number and poor ionic conductivity, which mainly result from the simultaneous migration of Na+ and anions, the high crystallinity of PEO, and the low concentration of free Na+. Here, we report a high-performance PEO-based all-solid-state electrolyte for sodium batteries by introducing Na3SbS4 to interact with the TFSI anion in the salt and decrease the crystallinity of PEO. The optimal PEO/NaTFSI/Na3SbS4 electrolyte exhibits a remarkably enhanced Na+ transference number (0.49) and a high ionic conductivity of 1.33 × 10−4 S cm−1 at 45 °C. Moreover, we found that the electrolyte can largely alleviate Na+ depletion near the electrode surface in symmetric cells and, thus, contributes to stable and dendrite-free Na plating/stripping for 500 h. Furthermore, all-solid-state Na batteries with a 3,4,9,10-perylenetetracarboxylic dianhydride cathode exhibit a high capacity retention of 84% after 200 cycles and superior rate performance (up to 10C). Our work develops an effective way to realize a high-performance all-solid-state electrolyte for sodium batteries.

Graphical abstract: High-performance all-solid-state electrolyte for sodium batteries enabled by the interaction between the anion in salt and Na3SbS4

Supplementary files

Article information

Article type
Edge Article
Submitted
02 dez 2021
Accepted
22 fev 2022
First published
23 fev 2022
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2022,13, 3416-3423

High-performance all-solid-state electrolyte for sodium batteries enabled by the interaction between the anion in salt and Na3SbS4

Y. Lu, L. Li, Q. Zhang, Y. Cai, Y. Ni and J. Chen, Chem. Sci., 2022, 13, 3416 DOI: 10.1039/D1SC06745A

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