Issue 10, 2019

Aryl-platform-based tetrapodal 2-iodo-imidazolium as an excellent halogen bond receptor in aqueous medium

Abstract

An acyclic tetrapodal receptor (L4+-I)(4PF6)4− comprised of four 2-iodo-imidazolium motifs showed moderate to strong binding of halides through halogen bonding interactions in organic and aqueous media, with these binding levels established by performing isothermal titration calorimetry studies. Importantly, single crystals suitable for X-ray diffraction studies were obtained from both water and an acetonitrile–water binary solvent mixture, and exhibited halogen bonding interactions in the solid state.

Graphical abstract: Aryl-platform-based tetrapodal 2-iodo-imidazolium as an excellent halogen bond receptor in aqueous medium

Supplementary files

Article information

Article type
Communication
Submitted
15 dez 2018
Accepted
07 jan 2019
First published
07 jan 2019

Chem. Commun., 2019,55, 1506-1509

Aryl-platform-based tetrapodal 2-iodo-imidazolium as an excellent halogen bond receptor in aqueous medium

S. Chakraborty, S. Maji, R. Ghosh, R. Jana, A. Datta and P. Ghosh, Chem. Commun., 2019, 55, 1506 DOI: 10.1039/C8CC09937E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements