Issue 37, 2011

Selective oxidative debenzylation of mono- and oligosaccharides in the presence of azides§

Abstract

When using benzyl ethers as permanent protecting groups in oligosaccharide synthesis selective oxidative debenzylation with NaBrO3 + Na2S2O4 under biphasic conditions is efficient and compatible with anomeric azides and many other functions.

Graphical abstract: Selective oxidative debenzylation of mono- and oligosaccharides in the presence of azides

Supplementary files

Article information

Article type
Communication
Submitted
29 jun 2011
Accepted
29 jul 2011
First published
18 ago 2011

Chem. Commun., 2011,47, 10485-10487

Selective oxidative debenzylation of mono- and oligosaccharides in the presence of azides

M. Niemietz, L. Perkams, J. Hoffman, S. Eller and C. Unverzagt, Chem. Commun., 2011, 47, 10485 DOI: 10.1039/C1CC13884G

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