Issue 37, 2011
From the journal:

Chemical Communications

Rhodium-catalyzed asymmetric addition of arylboroxines to β-alkoxyacrylate esters†

Takahiro Nishimura,*a   Atsuyuki Kasai,a   Makoto Nagaosaa  and  Tamio Hayashi*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan
E-mail: tnishi@kuchem.kyoto-u.ac.jp, thayashi@kuchem.kyoto-u.ac.jp
Fax: +81 75 753 3988
Tel: +81 75 753 3983

Abstract

Asymmetric addition of arylboroxines to β-alkoxyacrylate esters proceeded in the presence of a rhodium complex coordinated with a chiral diene ligand to give high yields of β-alkoxy-β-arylcarboxylic acid esters with very high enantioselectivity.

Graphical abstract: Rhodium-catalyzed asymmetric addition of arylboroxines to β-alkoxyacrylate esters

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Article information

DOI
https://doi.org/10.1039/C1CC14150C
Article type
Communication
Submitted
11 Jul 2011
Accepted
29 Jul 2011
First published
17 Aug 2011

Chem. Commun., 2011,47, 10488-10490

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Rhodium-catalyzed asymmetric addition of arylboroxines to β-alkoxyacrylate esters

T. Nishimura, A. Kasai, M. Nagaosa and T. Hayashi, Chem. Commun., 2011, 47, 10488 DOI: 10.1039/C1CC14150C

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