Pancake bonding phenomenology is applied for the first time in a bioorganic system, the pigment eumelanin, via a hydration-induced decrease of the interplanar distance down to 3.19 Å. The observation explains the long-term inconsistency between electron paramagnetic resonance and muon spin relaxation data for eumelanin.
P. A. Abramov, O. I. Ivankov, A. B. Mostert and K. A. Motovilov, Phys. Chem. Chem. Phys., 2023, 25, 16212 DOI: 10.1039/D3CP01773G
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