Issue 5, 2014

Vanadium-catalyzed C(sp3)–H fluorination reactions

Abstract

Vanadium(III) oxide catalyzes the direct fluorination of C(sp3)–H groups with Selectfluor. This reaction is operationally simple. The catalyst and the reaction by-product can be removed easily by filtration. Using this method, a fluorine atom can be introduced to the tertiary position of 1,4-cineole and L-menthone selectively.

Graphical abstract: Vanadium-catalyzed C(sp3)–H fluorination reactions

Supplementary files

Article information

Article type
Research Article
Submitted
27 fev 2014
Accepted
24 mar 2014
First published
25 mar 2014

Org. Chem. Front., 2014,1, 468-472

Author version available

Vanadium-catalyzed C(sp3)–H fluorination reactions

J. Xia, Y. Ma and C. Chen, Org. Chem. Front., 2014, 1, 468 DOI: 10.1039/C4QO00057A

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