Radical vinylation was investigated using vinyl bromides with an electron-withdrawing substituent at the β-position. The vinylation of 1,3-dioxolanes proceeded well to give 2-vinyl-1,3-dioxolanes in good yields. The α-vinylation of N-acylpyrrolidines also proceeded well to give 2-vinyl-N-acylpyrrolidines.
T. Kippo, Y. Kimura, A. Maeda, H. Matsubara, T. Fukuyama and I. Ryu, Org. Chem. Front., 2014, 1, 755 DOI: 10.1039/C4QO00138A
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