Issue 59, 2012

P–P Menschutkin preparation of prototypical phosphinophosphonium salts

Abstract

Reactions of Me3P with alkyl- or arylchlorophosphines yield phosphinophosphonium salts in quantitative yields, demonstrating a Menschutkin P–P methodology that has potentially broad application for element–element bond formation.

Graphical abstract: P–P Menschutkin preparation of prototypical phosphinophosphonium salts

Supplementary files

Article information

Article type
Communication
Submitted
29 apr 2012
Accepted
31 mei 2012
First published
20 jun 2012

Chem. Commun., 2012,48, 7359-7361

P–P Menschutkin preparation of prototypical phosphinophosphonium salts

S. S. Chitnis, E. MacDonald, N. Burford, U. Werner-Zwanziger and R. McDonald, Chem. Commun., 2012, 48, 7359 DOI: 10.1039/C2CC33082B

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