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Issue 59, 2012
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Oxozinc carboxylates: a predesigned platform for modelling prototypical Zn-MOFs' reactivity toward water and donor solvents

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Abstract

Two unique adducts of an oxozinc carboxylate cluster with H2O and THF were isolated and structurally characterized, [Zn44-O)(O2CR)6(H2O)(THF)]·2(THF) and [Zn44-O)(O2CR′)6(THF)3] (where R = benzoate and R′ = 9-antracenecarboxylate anion). The study shows that the zinc centers of the Zn4O core can easily form unique coordination environments without breaking of the Zn–Ocarboxylate bonds.

Graphical abstract: Oxozinc carboxylates: a predesigned platform for modelling prototypical Zn-MOFs' reactivity toward water and donor solvents

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Article information


Submitted
29 Apr 2012
Accepted
30 May 2012
First published
31 May 2012

Chem. Commun., 2012,48, 7362-7364
Article type
Communication

Oxozinc carboxylates: a predesigned platform for modelling prototypical Zn-MOFs' reactivity toward water and donor solvents

W. Bury, I. Justyniak, D. Prochowicz, Z. Wróbel and J. Lewiński, Chem. Commun., 2012, 48, 7362
DOI: 10.1039/C2CC33094F

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