Issue 5, 2014
From the journal:

Organic Chemistry Frontiers

Visible-light photocatalytic oxidation of 1,3-dicarbonyl compounds and carbon–carbon bond formation†‡

Marion Daniel,ab   Louis Fensterbank,*ab   Jean-Philippe Goddard*abc  and  Cyril Ollivier*ab  

* Corresponding authors

a Sorbonne Universités UPMC Univ Paris 06, UMR 8232, Institut Parisien de Chimie Moléculaire, 4 place Jussieu, C. 229, F-75005 Paris, France
E-mail: louis.fensterbank@upmc.fr, jean-philippe.goddard@uha.fr, cyril.ollivier@upmc.fr
Fax: +33(0)44277360

b CNRS, UMR 8232, Institut Parisien de Chimie Moléculaire, 4 place Jussieu, C. 229, F-75005 Paris, France

c Laboratoire de Chimie Organique et Bioorganique EA 4566, Université de Haute-Alsace, Ecole Nationale Supérieure de Chimie de Mulhouse, 3 rue Alfred Werner, F-68093 Mulhouse Cedex, France

Abstract

Visible-light photocatalytic oxidation of 1,3-dicarbonyl compounds, using Ru(bpy)3Cl2 as a photocatalyst and combining molecular oxygen and triphenylcarbenium as a new sacrificial acceptor, has been developed for carbon–carbon bond formation giving access to dimerization, allylation and polycyclization products.

Graphical abstract: Visible-light photocatalytic oxidation of 1,3-dicarbonyl compounds and carbon–carbon bond formation

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Article information

DOI
https://doi.org/10.1039/C4QO00071D
Article type
Research Article
Submitted
13 mrt 2014
Accepted
29 apr 2014
First published
30 apr 2014

Org. Chem. Front., 2014,1, 551-555

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Visible-light photocatalytic oxidation of 1,3-dicarbonyl compounds and carbon–carbon bond formation

M. Daniel, L. Fensterbank, J. Goddard and C. Ollivier, Org. Chem. Front., 2014, 1, 551 DOI: 10.1039/C4QO00071D

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