Issue 59, 2012
From the journal:

Chemical Communications

P–P Menschutkin preparation of prototypical phosphinophosphonium salts†‡

Saurabh S. Chitnis,a   Elizabeth MacDonald,b   Neil Burford,*ab   Ulrike Werner-Zwanzigerb  and  Robert McDonaldc  

* Corresponding authors

a Department of Chemistry, University of Victoria, Victoria, BC, Canada
E-mail: nburford@uvic.ca
Fax: + 1 250 721 7147
Tel: + 1 250 721 7150

b Department of Chemistry, Dalhousie University, Halifax, Canada

c X-ray Crystallography Laboratory, Department of Chemistry, University of Alberta, Edmonton, Alberta T6G2G2, Canada

Abstract

Reactions of Me3P with alkyl- or arylchlorophosphines yield phosphinophosphonium salts in quantitative yields, demonstrating a Menschutkin P–P methodology that has potentially broad application for element–element bond formation.

Graphical abstract: P–P Menschutkin preparation of prototypical phosphinophosphonium salts

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Article information

DOI
https://doi.org/10.1039/C2CC33082B
Article type
Communication
Submitted
29 apr 2012
Accepted
31 mei 2012
First published
20 jun 2012

Chem. Commun., 2012,48, 7359-7361

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P–P Menschutkin preparation of prototypical phosphinophosphonium salts

S. S. Chitnis, E. MacDonald, N. Burford, U. Werner-Zwanziger and R. McDonald, Chem. Commun., 2012, 48, 7359 DOI: 10.1039/C2CC33082B

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