Issue 74, 2016

Probing and evaluating anion–π interaction in meso-dinitrophenyl functionalized calix[4]pyrrole isomers

Abstract

We investigate anion–π binding modes in a cis-isomer of 3,5-dinitrophenyl-substituted calix[4]pyrrole with various anions via X-ray crystallographic analyses and compare its binding affinities with those of the corresponding trans-isomer. Sandwich-type anion–π interactions prove to not only enhancing anion binding abilities but also altering the anion-binding selectivity of the calix[4]pyrrole framework.

Graphical abstract: Probing and evaluating anion–π interaction in meso-dinitrophenyl functionalized calix[4]pyrrole isomers

Supplementary files

Article information

Article type
Communication
Submitted
31 mei 2016
Accepted
12 aug 2016
First published
15 aug 2016

Chem. Commun., 2016,52, 11139-11142

Probing and evaluating anion–π interaction in meso-dinitrophenyl functionalized calix[4]pyrrole isomers

A. Kim, R. Ali, S. H. Park, Y. Kim and J. S. Park, Chem. Commun., 2016, 52, 11139 DOI: 10.1039/C6CC04562F

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