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Four Cd(II)/diene coordination polymers (CPs) with similar 1D chain motifs exhibit different photosalient (PS) behaviours in response to UV light. The [2+2] photoreaction between the C[double bond, length as m-dash]C groups within these CPs results in diverse PS behaviours of their crystals with different C[double bond, length as m-dash]C pair arrangements. The interesting PS behaviours of these CPs can be applied in design and fabrication of advanced photoactuating materials.

Graphical abstract: Tunable photosalient behaviours within coordination polymers via functional molecular prearrangements

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