Issue 11, 2019

Germylone-bridged bimetallic Ir and Rh complexes

Abstract

The reactions of germylone 1 with one equivalent of [M(COD)Cl]2 (M = Ir, Rh) afforded the germylone-bridged bimetallic complexes 2 and 3, which have been spectroscopically and structurally characterized. Density functional theory (DFT) studies reveal the relatively strong interactions between the Ge atom and these metals. By the reaction of [Rh(COD)Cl]2 with CO followed by addition of 1, a complex 4 involving a Rh–Ge–Rh–Ge–Rh chain was also synthesized.

Graphical abstract: Germylone-bridged bimetallic Ir and Rh complexes

Supplementary files

Article information

Article type
Communication
Submitted
11 ဇန် 2019
Accepted
07 ဖေ 2019
First published
07 ဖေ 2019

Dalton Trans., 2019,48, 3555-3559

Germylone-bridged bimetallic Ir and Rh complexes

B. Su, K. Ota, Y. Li and R. Kinjo, Dalton Trans., 2019, 48, 3555 DOI: 10.1039/C9DT00145J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements