Issue 100, 2023

Synthesis of unsymmetrical ketones via dual catalysed cross-coupling of α,β-unsaturated carboxylic acids with aryldiazonium salts

Abstract

A visible light-enabled synthesis of unsymmetrical ketones has been accomplished by the cross-coupling of α,β-unsaturated carboxylic acids and aryldiazonium salts embracing a synergistic eosin Y and Co(OAc)2·4H2O catalysis. The reaction involves decarboxylative aerobic C[double bond, length as m-dash]C bond cleavage, and is endowed with the creation of new C–C and C–O bonds with good substrate scope.

Graphical abstract: Synthesis of unsymmetrical ketones via dual catalysed cross-coupling of α,β-unsaturated carboxylic acids with aryldiazonium salts

Supplementary files

Article information

Article type
Communication
Submitted
03 အောက် 2023
Accepted
20 နို 2023
First published
20 နို 2023

Chem. Commun., 2023,59, 14827-14830

Synthesis of unsymmetrical ketones via dual catalysed cross-coupling of α,β-unsaturated carboxylic acids with aryldiazonium salts

S. Chand, A. K. Sharma, A. K. Pandey and K. N. Singh, Chem. Commun., 2023, 59, 14827 DOI: 10.1039/D3CC04898E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements