Issue 64, 2024

Modulated synthesis of hcp MOFs for preferential CO2 capture

Abstract

We herein show that the μ2-OH bridging groups in the double M12O8(OH)14 clusters of hcp UiO-66 could act as a preferential CO2 sorption site, compared to fcu UiO-66. As such, hcp-UiO-66-0.015 shows a high binary CO2 sorption capacity of 0.31 mmol g−1 and CO2/N2 (15/85) mixture selectivity of 87 at 298 K and 1 bar, which holds great potential for post-combustion CO2 capture.

Graphical abstract: Modulated synthesis of hcp MOFs for preferential CO2 capture

Supplementary files

Article information

Article type
Communication
Submitted
27 ဧပြီ 2024
Accepted
05 ဇူ 2024
First published
08 ဇူ 2024

Chem. Commun., 2024,60, 8395-8398

Modulated synthesis of hcp MOFs for preferential CO2 capture

J. Zhang, M. N. Khan, Z. Hu and J. Zou, Chem. Commun., 2024, 60, 8395 DOI: 10.1039/D4CC01985G

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