Issue 64, 2024

Modulation of Fe–Fe distance and spin in diiron complexes using tetradentate ligands with different flanking donors

Abstract

Here we report the synthesis and characterization of diiron complexes containing triaryl N4 and N2S2 ligands derived from o-phenylenediamine. The complexes display significant differences in Fe–Fe distances and magnetic properties that depend on the identity of the flanking NMe2 and SMe donor groups.

Graphical abstract: Modulation of Fe–Fe distance and spin in diiron complexes using tetradentate ligands with different flanking donors

Supplementary files

Article information

Article type
Communication
Submitted
27 May 2024
Accepted
10 Jul 2024
First published
19 Jul 2024
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2024,60, 8399-8402

Modulation of Fe–Fe distance and spin in diiron complexes using tetradentate ligands with different flanking donors

K. D. Spielvogel, E. J. Campbell, S. R. Chowdhury, F. Benner, S. Demir, G. P. Hatzis, H. R. Petras, D. Sembukuttiarachchige, J. J. Shepherd, C. M. Thomas, B. Vlaisavljevich and S. R. Daly, Chem. Commun., 2024, 60, 8399 DOI: 10.1039/D4CC02522A

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