Themed collection Journal of Materials Chemistry A Recent Review Articles

323 items - Showing page 1 of 5
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Topological quantum materials in catalysis

Let's quantum: topological quantum materials offer high electron mobility, stable surface states, and resistance to contamination, making them ideal candidates for next-generation heterogeneous catalysts.

Graphical abstract: Topological quantum materials in catalysis
Open Access Accepted Manuscript - Perspective

Pressure-Tuned 2D Hybrid Perovskites: Emerging Insights and Future Opportunities

Open Access Perspective

Si anodes for Li+ batteries: what is the ideal structure?

Quantitative governing equations are proposed to correlate structural features with performance as guiding principles to design porous p-Si structures for Li ion battery anodes.

Graphical abstract: Si anodes for Li+ batteries: what is the ideal structure?
Perspective

Precise design of MOF-derived single-atom catalysts with symmetric and asymmetric coordination for advanced lithium–sulfur batteries

Single-atom catalysts (SACs) have demonstrated great potential as ideal electrocatalytic hosts for sulfur cathodes in lithium–sulfur (Li–S) batteries.

Graphical abstract: Precise design of MOF-derived single-atom catalysts with symmetric and asymmetric coordination for advanced lithium–sulfur batteries
Open Access Perspective

Decoding pH-dependent electrocatalysis through electric field models and microkinetic volcanoes

This perspective highlights advances in capturing pH-dependent surface structures, reactivity, and mechanisms via electric field-based methods.

Graphical abstract: Decoding pH-dependent electrocatalysis through electric field models and microkinetic volcanoes
Open Access Perspective

Reducibility, adsorption energies, surface acidity – fundamental material properties for fast oxygen exchange

Combining a comprehensive discussion of literature with new mechanistic insights, we derive two fundamental design principles for material systems with optimal oxygen exchange kinetics: a shallow O 2p band center and a low work function.

Graphical abstract: Reducibility, adsorption energies, surface acidity – fundamental material properties for fast oxygen exchange
Perspective

Electrochemical impedance spectroscopy measurements of solid oxide cells: beyond open circuit voltage conditions

This work emphasizes the importance of performing electrochemical impedance spectroscopy analyses in loading mode rather than under open circuit voltage conditions.

Graphical abstract: Electrochemical impedance spectroscopy measurements of solid oxide cells: beyond open circuit voltage conditions
Open Access Perspective

Tribocatalysis: a successful marriage of triboelectricity and heterogeneous catalysis

We discuss how tribocatalysis utilizes friction-generated charges to drive chemical transformations. The proposed mechanistic understanding, catalyst design, and future research directions are examined.

Graphical abstract: Tribocatalysis: a successful marriage of triboelectricity and heterogeneous catalysis
Perspective

Disorder by design: high-entropy oxides as next generation thermoelectric materials

Entropy-engineered oxides for thermoelectric energy.

Graphical abstract: Disorder by design: high-entropy oxides as next generation thermoelectric materials
Perspective

Beyond traditional TOF: unveiling the pitfalls in electrocatalytic active site determination

TOF reflects intrinsic catalytic activity by measuring per-site efficiency, unlike current density. Accurate TOF estimation requires identifying true active sites and RDS, enabling rational design of efficient electrocatalysts for sustainable water splitting.

Graphical abstract: Beyond traditional TOF: unveiling the pitfalls in electrocatalytic active site determination
Perspective

Repurposing PVA-based slime to address electrolyte challenges in portable electrochemical devices

PVA-based slime is an unexplored, cost-effective, and spill-proof alternative to conventional electrolytes. Its inherent ionic conductivity makes it a promising electrolyte for portable electrochemical surface-monitoring probes.

Graphical abstract: Repurposing PVA-based slime to address electrolyte challenges in portable electrochemical devices
Perspective

Stabilizing ultrafine intermetallics on carbon supports: from structural design to catalytic applications

Ultrafine intermetallics (<5 nm) offer unique catalytic properties but face sintering challenges. We highlight carbon-supported synthesis strategies for precise control, focusing on electrocatalytic applications and future directions.

Graphical abstract: Stabilizing ultrafine intermetallics on carbon supports: from structural design to catalytic applications
Perspective

Ordered energy conversion systems inspired from the biological world

In addressing the urgent challenges facing the energy industry, this perspective emphasizes the importance of offering efficient, clean and low-carbon ordered energy conversion systems by integrating biology and engineering.

Graphical abstract: Ordered energy conversion systems inspired from the biological world
Open Access Perspective

On the use of bioprecursors for sustainable silicon-based anodes for Li-ion batteries

Plants and protists: promising sources for Si-based Li-ion battery anodes.

Graphical abstract: On the use of bioprecursors for sustainable silicon-based anodes for Li-ion batteries
Perspective

How common is it to get an OER overpotential that is <250 mV?

This work raises concerns about the unintentional mistakes made by researchers developing OER electrocatalysts by overlooking the fundamentals.

Graphical abstract: How common is it to get an OER overpotential that is <250 mV?
Perspective

Unveiling the significance of working electrode substrates in electrocatalytic water splitting for sustainable hydrogen energy production

This perspective highlights how electrode substrate choice critically affects electrocatalyst performance in water splitting, guiding researchers to design better catalysts by leveraging each substrate’s unique properties.

Graphical abstract: Unveiling the significance of working electrode substrates in electrocatalytic water splitting for sustainable hydrogen energy production
Perspective

Recent advancements in metal–organic frameworks (MOFs) for flexible supercapacitors aimed at wearable technology

Flexible supercapacitors have made significant progress, as they can be integral to the wearable technology field due to their unique ability to allow seamless movement for the wearer.

Graphical abstract: Recent advancements in metal–organic frameworks (MOFs) for flexible supercapacitors aimed at wearable technology
Perspective

Advances and industrialization of LiFePO4 cathodes in electric vehicles: challenges, innovations, and future directions

Evolution, research focus, industrialization and recovery techniques of LiFePO4 cathodes are reviewed, highlighting their critical role in meeting energy demands, especially in EVs.

Graphical abstract: Advances and industrialization of LiFePO4 cathodes in electric vehicles: challenges, innovations, and future directions
Perspective

From lab to market: the future of zinc–air batteries powered by MOF/MXene hybrids

Zinc–air batteries (ZABs) stand at the forefront of energy storage technologies. However, challenges like slow kinetics and low rechargeability persist. MOF–MXene hybrids enhance performance, enabling sustainable ZAB technology.

Graphical abstract: From lab to market: the future of zinc–air batteries powered by MOF/MXene hybrids
From the themed collection: Journal of Materials Chemistry A HOT Papers
Perspective

Sulfur element achieves rapid and stable migration of Li+ in oxide cathode materials

Higher energy density can be obtained by increasing the charging cut-off voltage of Ni-rich materials to meet the range requirements of electric vehicles.

Graphical abstract: Sulfur element achieves rapid and stable migration of Li+ in oxide cathode materials
Open Access Perspective

Capacity-weighted figures-of-merit for battery transport metrics

Fast-charging materials are necessary for a battery-centric future. Ionic and electronic transport crucially determine performance where their capacity-weighted figures-of-merit account for performance across all states-of-charge.

Graphical abstract: Capacity-weighted figures-of-merit for battery transport metrics
Perspective

Recent advances in characterization of rechargeable battery materials via scanning probe microscopy

Scanning probe microscopy can be used to obtain topographical, mechanical, electrical, and electrochemical information on a wide range of materials in a variety of environments, including in situ and operando studies for rechargeable battery systems.

Graphical abstract: Recent advances in characterization of rechargeable battery materials via scanning probe microscopy
Perspective

Sorbent-based atmospheric water harvesting: engineering challenges from the process to molecular scale

Atmospheric water harvesting is an emerging technique that can potentially increase water access to water-constrained communities.

Graphical abstract: Sorbent-based atmospheric water harvesting: engineering challenges from the process to molecular scale
Review Article

Recent advances in the orbital modulation of multi-element nanoparticles for boosted catalytic performance

Multi-element nanoparticles (ME NPs) show unique and crucial roles in numerous electrochemical reactions involving conversion of energy, particularly in the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER).

Graphical abstract: Recent advances in the orbital modulation of multi-element nanoparticles for boosted catalytic performance
Accepted Manuscript - Review Article

The Application of Low-temperature Processed Metal Oxide Electron Transport Layer in Flexible Perovskite Solar Cell

Accepted Manuscript - Review Article

Recent Advances in Dimethyl Oxalate Hydrogenation: Integrating Catalyst Design with Reaction Engineering for Sustainable Production of C2 Oxygenates

Review Article

Single-atom alloys for photocatalytic applications: material innovation and light-driven reactivity

Single-atom alloys are presented through synthesis, mechanisms, and photocatalytic applications, highlighting atomic-level and alloying effects in light-driven catalysis.

Graphical abstract: Single-atom alloys for photocatalytic applications: material innovation and light-driven reactivity
Review Article

Practice and tactics in the construction of novel degradable plastics at polymer and molecular levels

The technology for achieving controlled degradation of plastics at the polymer and molecular levels has been comprehensively reviewed.

Graphical abstract: Practice and tactics in the construction of novel degradable plastics at polymer and molecular levels
Review Article

Defect structures in supercapacitor electrodes: non-oxide 2D materials and metal oxides

This review highlights how crystallographic and interfacial defects control charge storage in supercapacitors by modulating electronic structure, ion transport, and redox kinetics, ultimately shaping capacitive behavior and stability.

Graphical abstract: Defect structures in supercapacitor electrodes: non-oxide 2D materials and metal oxides
Review Article

Interface engineering in polymer thermoelectric composites: harnessing energy-filtering effects to overcome the Seebeck-conductivity trade-off

A systematic review of energy filtering (EF) engineering in polymer-based TE composites is presented. The effect of EF on ionic organic films, organic–inorganic composites, MXene-based hybrids and aerogel composites is analysed.

Graphical abstract: Interface engineering in polymer thermoelectric composites: harnessing energy-filtering effects to overcome the Seebeck-conductivity trade-off
Review Article

Lithium based battery systems: technological and environmental challenges and opportunities

The United Nations has prioritized decarbonization and reducing greenhouse gas emissions, leading nations to adopt policies for increased renewable energy use. Lithium-ion batteries are key to this shift, though they present challenges to overcome.

Graphical abstract: Lithium based battery systems: technological and environmental challenges and opportunities
Review Article

Polymorphs of VO2 and their MXene-based hybrid materials for energy storage applications

The well-defined crystal structure of VO2 polymorphs have gained significant attention as a promising electrode material. Furthermore, its composites with MXenes are summarized for efficient energy storage applications.

Graphical abstract: Polymorphs of VO2 and their MXene-based hybrid materials for energy storage applications
Review Article

Advancing HT-PEM fuel cell technology: durability and performance under start–stop conditions

This review highlights degradation mechanisms and emerging mitigation strategies for HT-PEM fuel cells under start–stop conditions, guiding the design of durable, high-performance energy systems.

Graphical abstract: Advancing HT-PEM fuel cell technology: durability and performance under start–stop conditions
Accepted Manuscript - Review Article

Research progress on the preparation of cobalt-based oxide catalysts with different morphologies and their application for catalytic purification of air pollutants

Accepted Manuscript - Review Article

Ba(Zr, Ce)O3-Based Proton-Conducting Solid Oxide Electrolysis Cells for Efficient Hydrogen Production

From the themed collection: Journal of Materials Chemistry A HOT Papers
Review Article

Tailored CEI architectures to boost high-performance solid-state Zn-ion batteries

Cathode interface modification involves stabilizing CEI, building artificial CEI, boosting mechanics, inhibiting metal dissolution, and more.

Graphical abstract: Tailored CEI architectures to boost high-performance solid-state Zn-ion batteries
Open Access Accepted Manuscript - Review Article

A Review of Methanol-to-Olefins Conversion over SAPO-34: Catalyst Design, Mechanisms, and Kinetics

Review Article

Optimization strategies for an electrospinning-based wearable strain sensor: from materials to structure

This review summarizes electrospinning wearable strain sensor optimization, focusing on materials/structure to boost sensing performance. It explores health monitoring and human–machine interfaces, offering future development guidelines.

Graphical abstract: Optimization strategies for an electrospinning-based wearable strain sensor: from materials to structure
Review Article

Porous organic cages for radionuclide and heavy metal adsorption: structure–activity relationships

This work provides a closed-loop iterative strategy to develop POCs for adsorbing radionuclides and heavy metals, encompassing “synthetic strategy → structure–function analysis → performance feedback → strategy optimization.”

Graphical abstract: Porous organic cages for radionuclide and heavy metal adsorption: structure–activity relationships
Review Article

Regulating the interfacial stability of aqueous zinc-ion batteries via the introduction of organic functional molecules

Organic materials are promising regulators for stabilizing zinc anodes in AZIBs. This review highlights recent advances in organic interphases and electrolyte additives, explaining how organic materials regulate interfacial stability.

Graphical abstract: Regulating the interfacial stability of aqueous zinc-ion batteries via the introduction of organic functional molecules
Review Article

Structural engineering of carbon-based cathodes for advanced aqueous Zn–CO2 batteries: from macroscopic architectures to atomic-level manipulation

This review introduces the latest progress of Zn–CO2 batteries from the aspects of battery systems, electrolytes, electrodes, while the structural engineering of carbon cathodes at both the macroscopic level and the atomic level is summarized.

Graphical abstract: Structural engineering of carbon-based cathodes for advanced aqueous Zn–CO2 batteries: from macroscopic architectures to atomic-level manipulation
Review Article

Coordination force-led multifunctional molecules for efficient perovskite solar cells

Three typical types of multifunctional molecules used in PSCs and their corresponding functional groups.

Graphical abstract: Coordination force-led multifunctional molecules for efficient perovskite solar cells
Review Article

Lithium alloy anodes for all-solid-state lithium batteries: from failure mechanism to performance-oriented design

This review addresses the challenges faced by all-solid-state lithium metal batteries (ASSLMBs), analyzes the properties of lithium alloys, summarizes the recent applications of lithium alloy anodes in ASSLMBs, and presents outlooks.

Graphical abstract: Lithium alloy anodes for all-solid-state lithium batteries: from failure mechanism to performance-oriented design
Review Article

From activity to stability: dissolution-mediated surface reconstruction and redeposition in transition metal-based electrocatalysts

A comprehensive review on the structural reconstruction and associated dissolution/redeposition equilibria of the electrocatalysts during reactions is proposed, which is pivotal for addressing the delicate balance between activity and stability.

Graphical abstract: From activity to stability: dissolution-mediated surface reconstruction and redeposition in transition metal-based electrocatalysts
Review Article

Biomimetic applications inspired by waxberry (Myrica rubra): structure, functionality, and future perspectives

This review aims to provide a comprehensive understanding of waxberry-like structures, from their unique design and synthesis to their functional advantages and application potential.

Graphical abstract: Biomimetic applications inspired by waxberry (Myrica rubra): structure, functionality, and future perspectives
Review Article

Hypercrosslinked polymers (HCPs) for CO2 capture and catalytic conversion: synthesis, functionalization, and applications

The escalating concentration of atmospheric carbon dioxide (CO2), primarily driven by fossil fuel consumption, presents critical challenges to environmental sustainability and climate change mitigation.

Graphical abstract: Hypercrosslinked polymers (HCPs) for CO2 capture and catalytic conversion: synthesis, functionalization, and applications
Open Access Accepted Manuscript - Review Article

Silver–Bismuth Perovskite-Inspired Materials: Chemistry, Optoelectronic Properties, and Emerging Applications in Photovoltaics and Beyond

Accepted Manuscript - Review Article

Patterned Electrodes for Advanced Energy Conversion and Storage: From Precision Engineering to Practical Applications

Accepted Manuscript - Review Article

Unravelling the HER Activity of Functionalized Biochar: A Pathway to Cost-Effective Electrocatalysis

Review Article

Recent progress on ZnIn2S4-based composite photocatalysts for photocatalytic hydrogen production coupling organic synthesis

In this review, we systematically summarize the structure, modification method and photocatalytic hydrogen production coupling organic reaction applications of ZnIn2S4-based composites.

Graphical abstract: Recent progress on ZnIn2S4-based composite photocatalysts for photocatalytic hydrogen production coupling organic synthesis
Accepted Manuscript - Review Article

Advancements in Thermoelectric Hydrogels: Structural Design and Material Innovation for Biomedical and Wearable Applications

Review Article

Engineering MoS2-based electrocatalysts for water splitting: a comprehensive review of doping, heterostructures, and support integration strategies

The article offers a thorough analysis of MoS2, including its crystallographic phases (1T, 2H, and 3R), basic structural, optical, electrical, mechanical, and thermal characteristics, as well as synthesis and characterisation methods.

Graphical abstract: Engineering MoS2-based electrocatalysts for water splitting: a comprehensive review of doping, heterostructures, and support integration strategies
Review Article

Awakening the substrate: design of metal foam electrodes for water electrolysis

Metal foams, combining porosity and conductivity, are ideal self-supporting electrodes. This review outlines advances in their surface and structural design, providing insights and challenges for sustainable hydrogen energy systems.

Graphical abstract: Awakening the substrate: design of metal foam electrodes for water electrolysis
Open Access Review Article

Removal of radioactive elements from nuclear wastewater using metal–organic frameworks: a comprehensive analysis using DFT and meta-analysis

Metal–organic frameworks (MOFs) have great potential in nuclear wastewater treatment.

Graphical abstract: Removal of radioactive elements from nuclear wastewater using metal–organic frameworks: a comprehensive analysis using DFT and meta-analysis
Open Access Review Article

Quinones: understanding their electrochemistry, chemistry and degradation pathways to tap their full potential in aqueous redox flow batteries

Quinones are prime candidates for aqueous redox flow batteries. This review discusses the chemistry of quinones and degradation pathways in aqueous solution, illuminating their pathway to successful implementation through case studies and examples.

Graphical abstract: Quinones: understanding their electrochemistry, chemistry and degradation pathways to tap their full potential in aqueous redox flow batteries
Review Article

MXene gel solar thermal evaporator: a novel pathway for seawater desalination

This review explores the properties, design, and synthesis of MXene materials and analyzes the unique advantages of MXene-based composite gels with polymers, nanomaterials, and biomass in seawater desalination.

Graphical abstract: MXene gel solar thermal evaporator: a novel pathway for seawater desalination
Review Article

Layered double hydroxide-based catalysts for seawater electrolysis at industrial current densities: advances and perspectives

Seawater electrolysis is of great significance for sustainable hydrogen production, particularly in coastal and offshore regions with abundant renewable energy but limited freshwater resources.

Graphical abstract: Layered double hydroxide-based catalysts for seawater electrolysis at industrial current densities: advances and perspectives
Review Article

Engineering asymmetric MOF composites toward high-efficiency catalytic reactions

Asymmetric metal–organic framework composites (AMOFs) have garnered increasing attention due to their distinctive functional properties, demonstrating considerable promise in catalysis, particularly as micro- and nano-structured catalysts.

Graphical abstract: Engineering asymmetric MOF composites toward high-efficiency catalytic reactions
From the themed collection: Journal of Materials Chemistry A HOT Papers
Open Access Accepted Manuscript - Review Article

A review on electrochemical CO2-to-CH4 conversion for a sustainable energy future: From electrocatalysts to electrolyzers

Accepted Manuscript - Review Article

Advances in Amine-Functionalized Metal Organic Frameworks for Carbon Capture

Accepted Manuscript - Review Article

Metal-Organic Frameworks for Photocatalytic CO2 Conversion: Bridging Fundamental Insights to Practical Solutions

Review Article

Opaque, transparent, and colored low-emissivity materials for mid-infrared thermal management

This review reveals how microstructural design simultaneously governs coloration and thermal radiation control for advanced passive thermal management materials.

Graphical abstract: Opaque, transparent, and colored low-emissivity materials for mid-infrared thermal management
Review Article

Advancements in water electrolysis: enhancing hydrogen and oxygen production efficiency through electrocatalyst design and urea oxidation

In light of growing energy shortages and environmental challenges, hydrogen energy has emerged as a promising renewable energy alternative to fossil fuels.

Graphical abstract: Advancements in water electrolysis: enhancing hydrogen and oxygen production efficiency through electrocatalyst design and urea oxidation
Open Access Review Article

Electrochemical etching of MXenes: mechanism, challenges and future outlooks

This review focuses on the eco-friendly electrochemical etching synthesis of MXenes and their cutting-edge advancements compared to the conventional strategy, highlighting the innovations, challenges, and future outlooks.

Graphical abstract: Electrochemical etching of MXenes: mechanism, challenges and future outlooks
Review Article

The role of single-crystal substrates in synthesis of low-dimensional materials by CVD and their applications in electrocatalysis

Single-crystal substrates have significant influence on the chemical vapor deposition (CVD) method for preparing low-dimensional materials.

Graphical abstract: The role of single-crystal substrates in synthesis of low-dimensional materials by CVD and their applications in electrocatalysis
Review Article

From atoms to algorithms: a review of machine learning approaches to cathode material innovation in zinc-ion batteries

This review explores how ML accelerates data-driven design and synthesis of Zn-ion batteries, addressing data gaps, interpretability, and validation while emphasizing standardized datasets, explainable AI, and experiment–theory integration.

Graphical abstract: From atoms to algorithms: a review of machine learning approaches to cathode material innovation in zinc-ion batteries
Review Article

Advances in perovskite-based functional fibers and fabrics: toward smart, sustainable, and wearable technologies

Perovskite materials have emerged as a class of multifunctional materials with exceptional optoelectronic, physical and chemical properties, which have aroused great interest in their applications in functional fibers and fabrics.

Graphical abstract: Advances in perovskite-based functional fibers and fabrics: toward smart, sustainable, and wearable technologies
Review Article

Taming polysulfide shuttle and lithium dendrites in lithium–sulfur batteries via all-/quasi-solid-state electrolytes: recent progress and future prospects

Two critical challenges impede the advancement of lithium–sulfur batteries: lithium dendrite growth and polysulfide shuttle. This review systematically examines diverse solutions leveraging various all-solid-state and quasi-solid-state electrolytes.

Graphical abstract: Taming polysulfide shuttle and lithium dendrites in lithium–sulfur batteries via all-/quasi-solid-state electrolytes: recent progress and future prospects
Review Article

Research progress of heterogeneous catalysts with different dimensional supports for catalytic hydrolysis of ammonia borane

This paper reviews the latest research progress in hydrogen production by AB hydrolysis from the perspective of supported catalysts of different dimensions and discusses their catalytic mechanism, synthesis methods and reaction processes.

Graphical abstract: Research progress of heterogeneous catalysts with different dimensional supports for catalytic hydrolysis of ammonia borane
Open Access Review Article

Exploring metal halide perovskites as active architectures in energy storage systems

Metal halide perovskites are expanding beyond photovoltaics, showing promise in lithium-ion batteries, supercapacitors, and photo-induced energy storage systems through their unique properties.

Graphical abstract: Exploring metal halide perovskites as active architectures in energy storage systems
323 items - Showing page 1 of 5

About this collection

This collection contains recent Review-type articles published by Journal of Materials Chemistry A, the home for high impact applications, properties and synthesis of exciting new materials for energy and sustainability.

New articles will be added to this collection as soon as possible after publication.

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