Issue 35, 2022

Crystalline radical cations of bis-BN-based analogues of Thiele's hydrocarbon

Abstract

Two radical cations of bis-BN-based analogues of Thiele's hydrocarbons were facilely synthesized, fully characterized, and theoretically investigated. One-electron oxidation leads to the reduced bond length alternation and NICS values of the central C4N2 rings, suggesting the decreasing antiaromatic character. The spin density of the radical cations is significantly delocalized over the central linkers with a small contribution from two terminal N-heterocyclic boryl units.

Graphical abstract: Crystalline radical cations of bis-BN-based analogues of Thiele's hydrocarbon

Supplementary files

Article information

Article type
Communication
Submitted
01 мар. 2022
Accepted
29 мар. 2022
First published
30 мар. 2022

Chem. Commun., 2022,58, 5391-5394

Crystalline radical cations of bis-BN-based analogues of Thiele's hydrocarbon

Z. Xie, Y. Dai, M. Bao, Z. Feng, W. Wang, C. Liu, X. Wang and Y. Su, Chem. Commun., 2022, 58, 5391 DOI: 10.1039/D2CC01254E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements